Styrenic block copolymers tps (SEBS) - Polimeros termoplasticos,elastomeros y aditivos



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Styrenic block copolymers tps (SEBS)

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TPS

Styrenic block copolymers tps (tpe-s)


Styrene-ethylene-butylene-styrene




In Mexpolimeros we offer a wide range compound of SBS and developed according to their needs, ensuring quality products and service. Our product range includes grades  block copolymer SEBS and SEPS are available from 3 ÷ 70 Shore A to 70 ShoreD. XPRENE EB has been specifically formulated for molding or two shots (2K) and develops a chemical bond when molded by injection molding a variety of plastic substrates . XPRENE EB is divided into a wide range of products such as soft touch, expandable, high temperature resistant, low compression set, halogen FR and many other specialty categories. EB XPRENE thermoplastic elastomers are freely configurable flow. The EB XPRENE class consists of products that can replace natural rubber TPV (thermoplastic vulcanizate).




What is SEBS




SEBS possess the mechanical properties of rubbers, and the processing characteristics of thermoplasts. This is related to their molecular structure.One of the most used thermoplastic rubbers in injection moulding is styrene‐ethylene/butylene‐styrene, SEBS. Styrene‐ethylene/butylene‐styrene is a block copolymer in which ethylene/butylene‐ block separates two styrene‐blocks.  Polymers derived from styrene-butadiene are synthetic rubbers that have virtually completely replaced the natural. SEBS is a hydrogenated thermoplastic styrenic elastomer with excellent weatherability and heat resistance that is produced by hydrogenation of styrene and butadiene block copolymers. SEBS-based compounds has excellent elastomeric properties and a rubberlike appearance, designed for injection moulding and co-moulding onto polyolefines. They have excellent U.V. stability and are also suitable for extrusion applications. There are many varients from pure transparent high elasticity grades to filled gasket grades.






Name - Symbol
              Chemical Formula



  • SEBS
  • TPE-S
  • HSBC
  • Styrene-ethylene-butylene-styrene
  • Styrene ethylene butylene styrene
  • TR
  • ISO 18064: TPS



SEBS polymer properties





  • Thermoplastic elastomers with the high elasticity and strength comparable to vulcanized rubber
  • Excellent weatherability and resistance to heat aging
  • Rubber elasticity retention over broad temperature range
  • Excellent flex resistance
  • Excellent chemical (acid, alkali, and alcohol) resistance
  • Low density - 0.89 to 0.97 g/cm3
  • Excellent compatibility with styrenic and olefinic resins, imparting high impact strength
  • High tensile strength and modulus
  • Good miscibility
  • Good wear resistance
  • Good electrical properties
  • High coefficien of friction



SEBS Mechanical and physical properties




The SEBS rubbers offer excellent impact resistance and low-temperature flexibility, are highly resistant to oxidation and ozone, and do not require vulcanization. Their degree of flexibility is a function of hardness, with their Shore A hardness ranging from 37 to 95. The SEBS rubbers and compounds exhibit excellent resistance to ozone. For prolonged outdoor exposure the addition of an ultraviolet absorber or carbon black pigment or both is recommended.




SEBS Thermal properties




These rubbers are serviceable from −75 to 105°C. They have excellent resistance to very low-temperature impact and bending. Their thermal life and aging properties are excellent, as is their abrasion resistance. Although the SEBS rubbers have poor flame resistance, compounding can improve their flame retardancy. This compounding reduces the operating temperature slightly.




SEBS Electrical properties




SEBS are typically good insulators with high relative electrical resistivity being nonpolar polar best. However, the electrical properties of the compounds of XPRENE EB are more dependent on the ingredients used in the formulation of the elastomer base. Our compunding of SEBS can be conductive antistatic by the incorporation of sufficient amounts of graphite, special types of carbon black, certain metal powders or polar products in the rubber mixture. However, the conductivity obtained by these means does not resemble that of metals.




SEBS Chemical properties




The chemical resistance of the SEBS rubbers is similar to that of natural rubber. However, some degradation in the compounds can be seen at long-term exposure to organic solvents, oils as well as fuels. Therefore tests should be carried out to determine the suitability of TPE in each application that requires chemical resistance. We recommend the tests to be performed under actual service conditions, as the resistance and absorption are highly dependent on the service temperature and other conditions of the end application.

These products have very good resistance to hydrolysis and to most dilute acids and alkalis. With some concentrated acids, it is necessary to compound the materials without fillers, since CaCO3 (Calcium Carbonate) reacts with acid. Resistance to many vegetable fats (unsaturated) is moderate, while resistance to animal fats (saturated) tends to be poor. Resistanceto lubricating oil, gasoline and other fuel and many solvents is also poor. Resistance to alcohol and glycol is good. Filled grades have moderately good and unfilled products somewhat better abrasion values.




SEBS Processability



SEBS can be injection moulded. Nozzles of injection moulding machine and mould have to be round and spacious because after the pressure should have enough time for interacting with the moulded part.  If there are many cavities in the mould, channels should be well balanced.  The gate of mould’s nozzle has to be at least half of part’s wall thickness and the minimum gate size 0.7 mm. Because SEBS is an elastic material, it is possible to use large undercuts. The amount of undercut depends heavily on hardness of used SEBS trade.  Usually it is necessary to use ejection plate on ejection before opening the mould because soft mass does not usually endure ejector pins. Mould shrinkage depends for SEBS grade and fluctuates between 0.5 ‐ 3.5 %.  This has to be taken into account when designing the mould cavity and ejection.  Gas removal channels’ depth should be from 0.02 to 0.05 mm depending also on SEBS grade.  Unsatisfactory gas removal leads to weak weld lines. Mould temperature should be relatively low (+ 40 °C).  Mass  temperature should be
from 170 to 220 °C.



SEBS Compound



It is produced by highly selective partial-hydrogenation of the SBS polymer, resulting in higher heat resistance than SBS elastomers and greater processability and low-temperature properties than fully hydrogenated SEBS elastomers, in addition to the inherent polymer characteristics and properties. By using stabilizers, to obtain higher UV resistance and aging behaviour as required in automotive interior and exterior applications.





SEBS Applications



The SEBS rubbers find applications for a wide variety of
general-purpose rubber items as well as in automotive, sporting goods, and other products. Many applications are found in theelectrical industry for such items as flexible cords, welding and booster cables, flame-resistant appliance wiring materials, and automotive primary wire insulation, car interiors, home furnishings, domestic electrical appliances, flippers & other diving equipment, ski-boots, skating shoes, gaskets, parts for tools, handles, door handles etc. Food grades and medical: tops for containers and bottles, and toys.



 

 

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PVP,Polivinil,de,pirrolidona,VCMA,Cloruro,de,vinilo,acrilato,de,metilo RF,Resorcina,formaldehído,VCMMA,Cloruro,de,vinilo,metacrilato,de,metilo SAN,Estireno,acrilonitrilo,VCOA,Cloruro,de,vinilo,acrilato,de,octilo SB,Estireno,butadieno,VCVAC,Cloruro,de,vinilo,acetato,de,vinilo SBR,Elastómero,de,estireno,butadieno,VCVDC,Cloruro,de,vinilo,cloruro,de,vinilideno SBS,Estireno,butadieno,estireno,VPE,Polietileno,reticulado SCR,Elastómero,de,estireno,cloropreno,VPSi Elastómero,de,metil,silicona,con,grupos,fenílicos,y,vinílicos SFRP,Plástico,reforzado,con,fibra,sintética,VSi,Elastómero,de,metil,silicona,con,grupos,vinílicos ,PP,PA6,PA66,PBT,PPS,PC,PC/ABS,fibra,vetro,talco,carbonato,bario,sfere,cavi,guaine,tubi,hose,belts,automotive,edilizia,elettrodomestico,tools,6722,112,r7,r8,r18,E,TEEE,TPC,ET,TPC,ET,TPC,ET,poliammidi,PPA,ABR Elastómero,de,éster,acrilicobutadieno ABS Acrilonitrilo,butadieno,estireno ACM Elastómero,de,éster,acrílico,2,cloroetilvini,éter ACS Acrilonitrilo,polietilenoclorado,estireno AES Acrílonítnlo,etilpropileno,estireno Al Polímeros,de,amida,imida AMMA Acrilonitrilo,metacrilato,de,metilo ANM Copolímero,de,éster,acrílico,acrilonitrilo ARP Plástico,reforzado,con,fibra,de,amianto ASA Acrilonitrilo,estireno,éster,acrílico AU Elastómero,de,poliuretano,de,poliéster BIIR Elastómero,de,isobutileno,isopropeno,bromado BK Baquelita BR Elastómero,de,butadieno BRP Plástico,reforzado,con,fibra,de,boro CA Acetato,de,celulosa CAB Acetobutirato,de,celulosa CAP Acetopropionato,de,celulosa CAR Fibra,de,carbono CEL Celuloide CF Cresol,formaldehído CFM Poli,(cloruro,de,trifluoretileno) CFRP Plástico,reforzado,con,fibra,de,carbono CHR Elastómero,de,epiclorhidrina CIIR Elastómero,de,isobutileno,isopreno,clorado CM Cauchos,de,polietileno,clorado CMG Carboxi,Metilcelulosa CN Nitrocelulosa CO Elastómero,de,epiclorhidrina CP Propionato,de,celulosa CPE Polietileno,clorado CPVC Policloruro,de,vinilo,clorado CR Elastómero,de,cloropreno CS Caseína CSM Polietileno,dorosulfonado CSR Polietileno,dorosulfonado CTFE Políclorotrifluoro,etileno ECO Copolímero,de,epjclorhidrina EEA Etileno,acrilato,de,etilo EP Etileno,propileno EP Epoxi EPD Terpolímero,de,etileno,propileno,dieno EPDM Terpolímero,de,etileno,propileno,dieno EPE Ester,epoxídico EPFV Epoxi,reforzado,con,fibra,de,vidrio EPM Copolímero,de,etileno,propileno EPR Copolímero,de,etileno,propileno EPS Poliestireno,expandible EPT Terpolimero,de,etileno,propileno,dieno ET Etileno,polisulfuro ETFE Etileno,tetrafluoroetileno EU Caucho,de,poliuretano,de,poliéteres EVA Etileno,acetato,de,vinilo EVAL Etileno,alcohol,vinílico EVRFV Ester,vinílico,reforzado,con,fibra,de,vidrio FEP Tetrafluoroetileno,hexafluoropropileno FPM Copolímero,de,fluoruro,de,vinilideno,y,hexafluoruro,de,propileno FSi Elastómero,metil,silicona,con,grupos,fluorados GPPS Poliestireno,cristal GR,I Elastómero,de,isobutileno,isopreno GR,N Elastómero,de,acrilonitrilo,butadieno GRP Plástico,reforzado,con,fibra,de,vidrio GR,S Elastómero,de,estireno,butadieno HDPE Polietileno,de,alta,densidad HIPS Poliestireno,alto,impacto IIR Elastómero,de,isobutileno,isopreno IM Poliisobutileno IR Elastómero,de,isopreno,(sintético) LCP Polímeros,de,cristal,liquido LOPE Polietileno,de,baja,densidad LLDPE Polietileno,lineal,de,baja,densidad MBS Metacrilato,de,metilo,butadieno,estireno MC Metilcelulosa MDPE Polietileno,de,media,densidad MF Melamina,formaldehído MFRP Plástico,reforzado,con,fibra,metálica MPF Metamina,fenol,formaldehído MWRP Plástico,reforzado,con,fibra,whiskers NBR Elastómero,de,acrilonitrilo,butadieno NCR Elastómero,de,acrilonitrilo,cloropreno NIR Elastómero,de,acrilonitrilo,isopreno NR Caucho,Natural,(elastómero,de,isopreno) OPP Polipropileno,orientado OPVC Policloruro,de,vinilo,orientado OSA Estireno,acrilonitrilo,modificado,con,olefina PA Poliamida PA11 Polímero,del,ácido,amino,11,undecanóico PA12 Polímero,de,dodecanolactama,1,12 PA6 Polímero,de,ε,caprolactama PA6/12 Copolímero,de,PA,6,y,PA,1,2 PA610 Polímero,de,hexametilendiamina,y,del,ácido,sebácico PA612 Polímero,de,hexametilendiamina,y,del,ácido,dodecanóico PA,6,3,T Polímero,de,trimetil,hexametilendiamina,y,ácido,tereftálico PA,66 Polímero,de,hexametilendiamina,y,del,ácido,adípico PA,66/610 Copolímero,de,hexametilendiamina,con,ácidos,adípico,y,sebácico PAA Poli,(ácido,acrílico) PAI Poliamida,imida PAN Poliacrilonitrilo PAPI Polifenil,isocianato,de,polimetileno PARFV Poliamida,reforzada,con,fibra,de,vidrio PB,1 Polibuteno,1 PB Polibutadieno PBAN Elastómero,de,acrilonitrilo,butadieno PBI Polibecimidazol PBR Elastómero,de,butadieno,piridina PBT Politereftalato,de,butileno PC Policarbonato PCTFE Policlorotrifluoroetileno PDAP Poli,(ftalato,de,dialilo) PE Polietileno PEAD Polietileno,de,alta,densidad PEBD Polietileno,de,baja,densidad PEC Polietileno,clorado PEEK Polieteretercetona PEI Polieterimida PEO Poli,(óxido,de,etileno} PEOX Poli,(óxido,de,etileno) PEP Polímero,de,etileno,propileno PES Poli,(éter,sulfona) PET Politereftalato,de,etileno PETG Politereftalato,de,etileno,modificado,con,glicol PF Fenol,formaldehído PFEP Polifluoroetilenpropileno Pl Poliimida PIB Poli,isobutileno PIR Poli,isocianurato PMI Polimetacrilamida PMMA Poli,(metacrilato,de,metilo) PMP Poli,(metil,4,penteno,1) PO Elastómero,de,poli,(óxido,de,propileno) POM Polioximetileno,poliformaldehído,poliacetal PP Polipropileno PPC Polipropileno,clorado PPO Poli,óxido,de,fenileno PPOX Poli,(óxido,de,polipropileno) PPRFV Polipropileno,reforzado,con,fibra,de,vidrio PPS Polísulfuro,de,fenileno PPSO Polifenisulfona PPSU Poli,(fenilén,sulfona) PRFV Plástico,reforzado,con,fibra,de,vidrio PS Poliestireno PSGP Poliestireno,cristal PSHI Poliestireno,alto,impacto PSBR Elastómero,de,piridina,estireno,butadieno PSE Poliestireno,expandible PSi Elastómero,de,metil,silicona PSU Polisulfona PIFE Politetrafluoroetileno PU Poliuretano PUR Poliuretano PVAC Poliacetato,de,vinilo PVAL Poli,(alcohol,vinílico) PVB Poli,(butirato,de,vinilo) PVC Poli,(cloruro,de,vinilo) PVCC Poli,(cloruro,de,vinilo),dorado PVDC Poli,(cloruro,de,vinilideno) PVDF Poli,(fluoruro,de,vinilideno) PVF Fluoruro,de,vinilideno PVFM Poli,(vinil,formaldehído) PVK Polivinilcarbazo,vinílico PVP Polivinil,de,pirrolidona RF Resorcina,formaldehído SAN Estireno,acrilonitrilo SB Estireno,butadieno SBR Elastómero,de,estireno,butadieno SBS Estireno,butadieno,estireno SCR Elastómero,de,estireno,cloropreno SFRP Plástico,reforzado,con,fibra,sintética SI Siliconas Si Elastómero,de,metil,silicona SIR Elastómero,de,estireno,isopreno SMA Estireno,anhídrido,maleico SMS Estireno,metil,estireno SP Poliéster,saturado TFE Politrifluoromocloroefileno TPE Elastómero,termoplástico TPU Poliuretano,termoplástico TPX Poli,4,metilpenteno UF Urea,formaldehído UHMWPE Polietileno,de,ultra,alto,peso,molecular UP Poliéster,insaturado,(plástico,de,uretano) VCE Cloruro,de,vinilo,etileno VCEMA Cloruro,de,vinilo,etileno,acrilato,de,metilo VCEVA Cloruro,de,vinilo,etileno,acetato,de,vinilo VCMA Cloruro,de,vinilo,acrilato,de,metilo VCMMA Cloruro,de,vinilo,metacrilato,de,metilo VCOA Cloruro,de,vinilo,acrilato,de,octilo VCVAC Cloruro,de,vinilo,acetato,de,vinilo VCVDC Cloruro,de,vinilo,cloruro,de,vinilideno VPE Polietileno,reticulado

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